LI Zheng
,
LIU Honglin
,
CHENG Zhaonian
,
CHEN Nianyi
,
Shanghai Institute of Metallurgy
,
Academia Sinica
,
Shanghai
,
ChinaZHOU Jiaju
,
Institute of Chemical Metallurgy
,
Academia Sinica
,
Beijing
,
China CHEN Nianyi
,
Professor
,
Shanghai Institute of Metallurgy
,
Academia Sinica
,
Shanghai 200050
,
China
金属学报(英文版)
The formability of complex flourides has been studied by chemical bond parameter-pattern recognition method. In a multi-dimensional space spanned by ionic radius, ionic polarizability, electronegativity and ionic charge of the metal elements, the binary complex flouride-forming systems and binary flouride systems without complex flouride formation distribute in different regions with a clear-cut boundary. The mathematical models obtained are useful for new complex flouride predicton.
关键词:
complex flouride
,
null
,
null
LIU Huizhou
,
YU Shuqiu
,
CHEN Jiayong
,
Institute of Chemical Metallurgy
,
Academia Sinica
,
Beijing
,
China LIU Huizhou
,
Institute of Chemical Metallurgy
,
Academia Sinica
,
Beijing 100080
,
China
金属学报(英文版)
Mechanism of extraction of Fe (III) from sulphate solution by primary amine N1923 and stripping of Fe loaded organic phase with dilute H_2SO_4 was investigated. The organic phase was characterized by FT-IR and photon correlation spectroscopy. The composition of extracted species as well as the content of H_2O in organic phase were determined. The dependence of both the rate of extraction and stripping on the formation of reverse micelle in primary amine (N1923)system has been confirmed. It is shown that the extraction of Fe(III) by primary amine sulphate may be related to the adduct formation or cation exchange reaction under different concentrations of H_2SO_4 in aqueous solution.
关键词:
Fe(III)
,
null
,
null
,
null
